The exciting beam has a power of 20 μW to prevent heating effects and it was focused on the sample with about 1 μm2 spot area through a fluorinated × 60 (NA = 0.9) Olympus microscope objective (Tokyo, Japan). Photoluminescence (PL) measurements were performed by pumping with the 488-nm line of an Ar+ laser.

Pump power was varied from Bortezomib nmr 1 to 200 mW, corresponding to a photon flux φ ranging from 3.1 × 1019 to 6.2 × 1021 cm−2 · s−1, and the laser beam was chopped through an acousto-optic modulator at a frequency of 55 Hz. The PL signal was analyzed by a single-grating monochromator and detected by a photomultiplier tube in the visible and by a liquid-nitrogen-cooled Ge detector or an IR-extended photomultiplier tube in the IR. Spectra were recorded with a lock-in amplifier using the acousto-optic modulator frequency as a reference. Time-resolved measurements were made by pumping the system

at a steady state, then switching off the laser beam, and detecting how the PL signal at a fixed wavelength decreases as a function of time. The overall time resolution of the system is 200 ns. Low-temperature measurements were performed by using a closed cycle He cryostat with the samples kept in vacuum at a pressure of 10−5 Torr. Results and discussion Figure 3a,b,c,d reports cross-sectional SEM images of Si/Ge NWs with different lengths obtained by the above-described metal-assisted wet etching approach by using increasing etching times. The images display dense (about 1011 NWs · cm−2 can be counted CA-4948 molecular weight in plain view; SEM images here not shown) and uniform arrays of NWs;

the length ranges from 1.0 (Figure 3a) to 2.7 μm (Figure 3d) and linearly depends on the etching time. Figure 3 Cross-sectional SEM analysis of MQW Si/Ge NWs. The images show NWs having lengths (a) 1.0, (b) 1.7, (c) 2.0, and (d) 2.7 μm. Raman measurements were used to estimate the NW mean size. Figure 4 shows the typical asymmetrically broadened Raman peak (solid line), due to the Si-Si stretching mode in optically confined crystalline Si nanostructures, detected on the Si/Ge NWs. The peak appears red shifted with respect to the Carnitine palmitoyltransferase II symmetric and sharper peak typical of bulk crystalline Si at 520 cm−1 (dashed line), reported in the same figure for comparison. The peak was fitted using a phenomenological model developed by Richter [16] and Campbell and Fauchet [17] for strongly confined phonons in nanocrystals and more recently adapted to Si NWs [2, 18]. The fit procedure gives a NW OSI-027 in vivo diameter of 8.2 ± 1.0 nm. Figure 4 Raman analysis of Si/Ge NWs. Comparison between the Raman spectra of Si/Ge NWs (blue continuous line) and bulk crystalline Si (red dashed line). A fit to the spectrum of Si/Ge NWs gives a diameter mean value of 8.2 ± 1.0 nm.