It reveals that the ZnO has a diameter of 5 to 10 μm and possesses a flower-like rough surface with petals emitted from the center. A typical ZnO flower image is shown in Figure 3b. Obviously, it buy GSK1838705A is about 1 μm at the widest point of the flower petals which are ended with a tip. CCI-779 ic50 Moreover, there are a large amount of holes on the petals, which can greatly enlarge the contact area between the organic dyes and ZnO. The ending part of saw-like petals is shown as inserted in Figure 3b. It can be seen that holes on the petals present an irregular shape with an average diameter below 100 nm. Considering the annealing process, it can be deduced that the holes are coming from amounts of gases evaporating with the decomposition
of the precursor at the relatively high temperature. The rough surfaces of ZnO provide a very good platform to locate Ag2O nanoparticles in high density during the co-precipitation process. Figure 3c GNS-1480 supplier shows
the morphology of the Ag2O nanoparticles obtained by the precipitation method. Obviously, the diameter of Ag2O particles is in the range of 100 to 500 nm. The enlarged view as inserted in Figure 3c shows that the Ag2O presents a rough surface with small spherical particles. For the composited sample, the morphology maintained the flower of ZnO, while Ag2O clusters were observed on the petals. From the insert in Figure 3d, it shows that the Ag2O cluster was composed of dozens of Ag2O nanoparticles. Figure 3 SEM images of pure ZnO, pure Ag 2 O, and ZnO-Ag 2 O composite. (a) Low-magnification SEM image of pure Farnesyltransferase ZnO, (b) high-magnification SEM image of pure ZnO, and (c, d) typical images of pure Ag2O and ZnO-Ag2O composite. It is known that MO dyes are usually chosen as model pollutants to simulate the actual photocatalytic degradation of organic pollutants. The degradation efficiency was calculated using Equation 1: (1) where C 0 represents the initial concentration, ΔC represents the changed concentration, C represents the reaction concentration, A 0 represents the initial absorbance, ΔA represents the changed
absorbance, and A represents the reaction absorbance of the MO at the characteristic absorption wavelength of 464 nm. In the experiments, the photocatalytic activities of the as-prepared samples with different ZnO-Ag2O composites, pure ZnO flowers, and Ag2O particles are shown in Figure 4a. Surprisingly, the ZnO-Ag2O (1:1) composite exhibits superior photocatalytic activity, which is higher than that of pure ZnO flowers and Ag2O nanoparticles; for example, the required time for an entire decolorization of MO over ZnO-Ag2O catalysts is less than or equal to 90 min, much shorter than the corresponding value over pure ZnO flower and Ag2O particles. Moreover, the correlation between the photocatalytic activity and the component mole ratios is shown in Figure 4b. Obviously, the photocatalytic activity increases gradually with an increase of the Ag2O mole ratios (1:1 > 6:1 > 28:1 > 0.5:1) except ZnO-Ag2O (0.5:1).